Antrasen birimi içeren aromatik monoamin bileşiğinin enzimatik ve oksidatif polimerizasyonu


Kolcu F. (Executive), Kaya İ.

Project Supported by Higher Education Institutions, 2024 - 2025

  • Project Type: Project Supported by Higher Education Institutions
  • Begin Date: January 2024
  • End Date: January 2025

Project Abstract

In this project, polymer products will be obtained in aqueous and organic media through the catalysis of 2-aminoanthracene in the presence of hydrogen peroxide oxidant, either with the presence of Horse Radish Peroxidase (HRP) enzyme and phosphate buffer or without buffer and enzyme catalysis at room temperature. The molecular weights, molecular weight distributions, and reaction efficiencies of the synthesized polymers or oligomers will be determined. The structure of the obtained polymers or oligomers will be elucidated using spectral methods such as 1H-NMR, 13C-NMR, FT-IR, UV-Vis. Characterization of monomers and their polymers or oligomers will be conducted through Gel Permeation Chromatography (GPC), Thermal Gravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), Cyclical Voltammetry (CV), and fluorescence analyses, with their electrochemical properties being determined. The morphological features of the polymers or oligomers will be identified through SEM analyses. As the synthesized polymers contain anthracene units, their optical and fluorescence properties will also be determined through UV-Vis and fluorescence spectrophotometer measurements.