Synthesis, characterization, and crystal structure of bis[4-(3 '-benzoyl)thiocarbamidophenyl]ether


Aydin F., Aykac D., Arslan N. B. , Kazak C.

CRYSTALLOGRAPHY REPORTS, cilt.59, ss.955-960, 2014 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 59 Konu: 7
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1134/s1063774514070050
  • Dergi Adı: CRYSTALLOGRAPHY REPORTS
  • Sayfa Sayıları: ss.955-960

Özet

The title compound, bis[4-(3'-benzoyl)thiocarbamidophenyl]ether, was synthesized by the reaction of benzoylisothiocyanate with 4,4'-diaminodiphenylether in aprotic solvent. The structure was determinated by means of elemental analysis and FT-IR, H-1-NMR, (1)3C-NMR and MS spectroscopic techniques. The crystal structure was characterized by X-ray syngle crystal analysis: orthorhombic, sp. gr. Pnna, Z = 4. In crystal packing, there are intramolecular hydrogen bond N-Ha <-O generating S(6) motif, and intermolecular hydrogen bond N-Ha <-S forming R (2) (2) (8) ring.