Metal-free, metallo-, oligomeric, and monomeric porphyrazine complexes of (3-thiopropyl anthraquinone-2-carboxylate) units

Gonca E.

JOURNAL OF COORDINATION CHEMISTRY, vol.68, no.7, pp.1142-1155, 2015 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 68 Issue: 7
  • Publication Date: 2015
  • Doi Number: 10.1080/00958972.2015.1018826
  • Journal Name: JOURNAL OF COORDINATION CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1142-1155
  • Çanakkale Onsekiz Mart University Affiliated: Yes

Abstract

Metal-free and metallo-porphyrazines (M = Mg, 2H, Co, Cu, Zn, or ClFe) with eight (3-thiopropyl anthraquinone-2-carboxylate) units appending on the periphery through flexible alkylthio-bridges have been synthesized through esterification of octakis(hydroxypropylthio) porphyrazinato magnesium with anthraquinone-2-carboxylic acid in the presence of dicyclohexylcarbodiimide (DCCI) and toluene-p-sulfonic acid. The synthesized compounds were characterized by FT-IR, UV-vis, (1) H and C-13 NMR, mass spectrometry, and elemental analysis.