Metal-free, metallo-, oligomeric, and monomeric porphyrazine complexes of (3-thiopropyl anthraquinone-2-carboxylate) units


Gonca E.

JOURNAL OF COORDINATION CHEMISTRY, cilt.68, ss.1142-1155, 2015 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 68 Konu: 7
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1080/00958972.2015.1018826
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Sayfa Sayıları: ss.1142-1155

Özet

Metal-free and metallo-porphyrazines (M = Mg, 2H, Co, Cu, Zn, or ClFe) with eight (3-thiopropyl anthraquinone-2-carboxylate) units appending on the periphery through flexible alkylthio-bridges have been synthesized through esterification of octakis(hydroxypropylthio) porphyrazinato magnesium with anthraquinone-2-carboxylic acid in the presence of dicyclohexylcarbodiimide (DCCI) and toluene-p-sulfonic acid. The synthesized compounds were characterized by FT-IR, UV-vis, (1) H and C-13 NMR, mass spectrometry, and elemental analysis.