Conduction Mechanism and Photo-Electochemical Performance of Copper Iodide Hole Transport Material-Based Perovskite Solar Cell


Srivastava M., Alheity M. A., Yahya M., Singh R., Gültekin S. S.

Journal of Electronic Materials, vol.52, no.7, pp.4351-4358, 2023 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 52 Issue: 7
  • Publication Date: 2023
  • Doi Number: 10.1007/s11664-023-10320-1
  • Journal Name: Journal of Electronic Materials
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, PASCAL, Applied Science & Technology Source, Chemical Abstracts Core, Chimica, Compendex, Computer & Applied Sciences, INSPEC
  • Page Numbers: pp.4351-4358
  • Keywords: copper iodide, efficiency, HTM, polymer electrolyte, PSC
  • Çanakkale Onsekiz Mart University Affiliated: Yes

Abstract

Perovskite solar cells have garnered the attention of researchers in recent years as they have been able to attain high efficiency within a short time. In the present study, the hybrid organic inorganic lead iodide perovskite has been used as the sensitizer. Successful fabrication of a hybrid lead halide perovskite sensitized solar cell (PSC) with copper iodide as a medium for transporting holes (HTM) has been performed in a sandwich structure. The synthesized CH3NH3PbI3 material and HTM have undergone various characterization processes, such as XRD, UV–Vis, SEM, and EDX. The present work is based on the synthesis of perovskite, HTM, and polymer electrolyte and their application in a PSC at room ambient following the sandwich structure. A planar WE/TiO2/CH3NH3PbI3/HTM/electrolyte/CE structure was fabricated through solution-processed spin-coating. The electrical properties of the PSC were measured through a solar simulator, and it attained an efficiency of 13.64%, with Voc=0.63V and Jsc=33mAcm2 with fill factor = 0.65. This work shows the sandwich-structured fabrication of the PSC in ambient condition with a considerably good efficiency which represents the novelty of the work.