The efficient removal of anionic and cationic dyes from aqueous media using hydroxyethyl starch-based hydrogels

Ilgın P., Özay H., Özay Ö.

CELLULOSE, cilt.27, sa.8, ss.4787-4802, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 27 Sayı: 8
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1007/s10570-020-03074-0
  • Dergi Adı: CELLULOSE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Compendex
  • Sayfa Sayıları: ss.4787-4802
  • Anahtar Kelimeler: Dye, Adsorption, Methyl violet, Methyl orange, Hydrogel, INTERPENETRATING POLYMER NETWORK, METHYLENE-BLUE REMOVAL, ADSORPTIVE REMOVAL, ACRYLIC-ACID, ORGANIC-DYES, ADSORBENT HYDROGEL, METAL-IONS, AZO-DYE, NANOPARTICLES, BEADS
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

In this study, hydroxyethyl starch (HES)-based hydrogels, hydroxyethyl starch/p(sodium acrylate) (HES/p(NaAAc)), hydroxyethyl starch/p(3-(acrylamidopropyl) trimethyl ammonium chloride) (HES/p(APTMACl)) and hydroxyethyl starch/p(acrylamide) (HES/p(AAm)) were synthesized with redox polymerization. The structural, morphological, and water absorption characterization of the synthesized hydrogels was investigated. HES-based hydrogels, containing anionic, cationic and neutral functional groups, were used for adsorption of methyl violet (MV) as a model cationic dye and methyl orange (MO) as a model anionic dye from aqueous media. HES/p(APTMACl) and HES/p(NaAAc) hydrogels had maximum adsorption values for MO and MV dyes of 238.1 mg/g and 185.2 mg/g. The isotherm and kinetic parameters for both dye adsorptions were determined. The adsorption isotherm and kinetic data were compatible with the Langmuir isotherm and pseudo-first-order kinetic models.