The synthesis and spectral characterization of N,N-Bis(2-{[(2-methyl-2-phenyl-1,3-dioxolan-4-yl)methyl] amino} ethyl)N ',N '-dihydroxyethanediimidamide and its complexes


Canpolat E., Kaya M., Ozturk O.

POLISH JOURNAL OF CHEMISTRY, cilt.78, ss.1843-1850, 2004 (SCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 78 Konu: 10
  • Basım Tarihi: 2004
  • Dergi Adı: POLISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.1843-1850

Özet

N,N-Bis(2-{[(2-methyl-2-phenyl-1,3-dioxolan-4-yl)methyl]amino)ethyl)N',N'-dihydr oxyethanediimidamide (LH2) has been synthesized and its mononuclear complexes with Co2+, Ni2+, Cu2+, Zn2+ and Cd2+ ions have been obtained. The mononuclear complexes indicated that the metal ions are ligand coordinated through the two N atoms, as do most of the vic-dioximes. The authenticity of the ligands and their complexes have been established by IR, H-1- and C-13-NMR spectra, UV-Visible spectroscopy, elemental analyses and magnetic susceptibility measurements.