The synthesis and spectral characterization of N,N-Bis(2-{[(2-methyl-2-phenyl-1,3-dioxolan-4-yl)methyl] amino} ethyl)N ',N '-dihydroxyethanediimidamide and its complexes


Canpolat E., Kaya M., Ozturk O.

POLISH JOURNAL OF CHEMISTRY, vol.78, no.10, pp.1843-1850, 2004 (Peer-Reviewed Journal) identifier

  • Publication Type: Article / Article
  • Volume: 78 Issue: 10
  • Publication Date: 2004
  • Journal Name: POLISH JOURNAL OF CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded
  • Page Numbers: pp.1843-1850

Abstract

N,N-Bis(2-{[(2-methyl-2-phenyl-1,3-dioxolan-4-yl)methyl]amino)ethyl)N',N'-dihydr oxyethanediimidamide (LH2) has been synthesized and its mononuclear complexes with Co2+, Ni2+, Cu2+, Zn2+ and Cd2+ ions have been obtained. The mononuclear complexes indicated that the metal ions are ligand coordinated through the two N atoms, as do most of the vic-dioximes. The authenticity of the ligands and their complexes have been established by IR, H-1- and C-13-NMR spectra, UV-Visible spectroscopy, elemental analyses and magnetic susceptibility measurements.