Akademik Veri Yönetim Sistemi
DYES AND PIGMENTS, cilt.227, 2024 (SCI-Expanded)
Preparation of oligo (aminophenols) was carried out by chemical oxidative and enzymatic oligomerization of 4amino-2,6-dibromophenol (ADBP). The former method required hydrogen peroxide as catalyst in an aqueous sodium hydroxide solution and the latter method was catalyzed by an enzyme, horseradish peroxidase, in 1,4dioxane resulting in the formation of (ADBP)-ox and (ADBP)-enz, respectively. For the structural confirmation for both of the synthesized oligomers were fulfilled using FT-IR, UV - vis and 1 H NMR and 13 C NMR instruments. The chemical oxidation with H 2 O 2 induced monodisperse particles in the sub-micron size. The thermal treatment of the oligomers at 1000 omicron C showed that the chemical oxidation resulted in (ADBP)-ox with higher residue% compared to enzymatic oxidation. Neutral ADBP underwent facile oxidation, leading to the formation of its corresponding oligomers, which were composed of head-to-tail or ortho -coupled constitutional moieties with lower optical and electrochemical band gaps than those of ADBP using two oligomerization routes. By analyzing the solvent effect on the absorption, lower optical band gaps of the synthesized oligomers were obtained in some selected solvents, pointing out them as semi-conductive material for the production of optoelectronic and electronic materials. By tuning the excitation wavelength, the fluorescence intensity of both of the oligomers was changed. DMF solution of (ADBP)-ox and (ADBP)-enz had a quantum yield of 17.6 % and 1.2 % for green and orange photoluminescence emission, respectively, with excellent photostability.