Unified treatment of one-range addition theorems for integer and non-integer n-STO, -GTO and -generalized exponential type orbitals with hyperbolic cosine in position, momentum and four-dimensional spaces

Guseinov I. I.

CHINESE PHYSICS B, vol.21, no.9, 2012 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 21 Issue: 9
  • Publication Date: 2012
  • Doi Number: 10.1088/1674-1056/21/9/093101
  • Journal Name: CHINESE PHYSICS B
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Çanakkale Onsekiz Mart University Affiliated: No

Abstract

Simpler formulas are derived for one-range addition theorems for the integer and noninteger n generalized exponential type orbitals, momentum space orbitals, and hyperspherical harmonics with hyperbolic cosine(GETO HC, GMSO HC, and GHSH HC) in position, momentum and four-dimensional spaces, respectively. The final results are expressed in terms of one-range addition theorems of complete orthonormal sets of psi(alpha)-exponential type orbitals, phi(alpha)-momentum space orbitals and z(alpha)-hyperspherical harmonics. We notice that the one-range addition theorems for integer and noninteger n-Sater type orbitals and Gaussian type orbitals in position, momentum and four dimensional spaces are special cases of GETO HC, GMSO HC, and GHSH HC. The theorems presented can be useful in the accurate study of the electronic structure of atomic and molecular systems.