Octakis(1 naphthylmethylthio) substituted porphyrazine derivatives


GONCA E. , Köseoğlu Y., Aktaş B., Gül A.

POLYHEDRON, cilt.23, ss.1845-1849, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 23 Konu: 10
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1016/j.poly.2004.05.001
  • Dergi Adı: POLYHEDRON
  • Sayfa Sayıları: ss.1845-1849

Özet

Magnesium porphyrazinate substituted with eight (1-naphthylmethylthio)groups on the peripheral positions has been synthesized by cyclotetramerization of 1,2-bis(1-naphthylmethylthio)maleonitrile in the presence of magnesium butanolate. The metal-free derivative was obtained by its treatment with trifluoroacetic acid and further reaction of this product with copper(II) acetate, zinc(II) acetate and cobalt(II) acetate led to the metal porphyrazinates (M=Cu, Zn, Co). These new compounds have been characterized by elemental analysis, together with FT-IR, H-1 NMR, UV-Vis and EPR spectral data. (C) 2004 Elsevier Ltd. All rights reserved.