A new oxidative reagent synthesis and its applications: Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC)

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Aydın F., Dersin S.

EUROPEAN JOURNAL OF CHEMISTRY, cilt.8, sa.2, ss.174-178, 2017 (Hakemli Dergi)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 8 Sayı: 2
  • Basım Tarihi: 2017
  • Dergi Adı: EUROPEAN JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Other Indexes
  • Sayfa Sayıları: ss.174-178
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

Tetrakis‐(2,4,6‐trimethylpyridine)silver(I) dichromate (T‐TMPSDC) was easily synthesized

by addition of 2,4,6‐trimethylpyridine to an aqueous precipitation of silver dichromate and

characterized thoroughly, using spectroscopic and others analytical methods such as FT‐IR,

1H NMR, 13C NMR, DTA, SEM‐EDS and XRD. When T‐TMPSDC was used as an oxidative

reagent, it showed selectivity in the oxidation of primary, secondary and benzylic alcohols to

their corresponding carbonyl compounds in