Voltammetric detection of biosorption of Co, Ni, Zn, Cd, Pb, and Cu on Hypnum cupressiforme Hedw. in aquatic media


YAYINTAŞ Ö., ÇAY S., ENGİN M. S., Ucarli O., SAĞLIKOĞLU G., YILMAZ S.

MONATSHEFTE FUR CHEMIE, vol.153, no.5-6, pp.419-425, 2022 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 153 Issue: 5-6
  • Publication Date: 2022
  • Doi Number: 10.1007/s00706-022-02921-z
  • Journal Name: MONATSHEFTE FUR CHEMIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core
  • Page Numbers: pp.419-425
  • Keywords: Competitive and non-competitive metal adsorption, Isotherm and kinetic, Moss, Adsorptive stripping voltammetry, Pollution removal, HEAVY-METAL DEPOSITION, HYLOCOMIUM-SPLENDENS, PLEUROZIUM-SCHREBERI, MOSSES, ADSORPTION, SORPTION, IONS
  • Çanakkale Onsekiz Mart University Affiliated: Yes

Abstract

In this study, the concentration of six heavy metal ions biosorbed at Hypnum cupressiforme Hedw. (HC), moss determined by voltammetric methods. While determining the optimum biosorption conditions, it was found that the amount of biosorbent 0.1 g, the contact time of metal ions-mosses is 30 min. The biosorption event shows that Ni2+ and Cu2+ appropriate the Langmuir isotherm and sequence of biosorption % was explained for covalent radii of these metals. Pb2+, Cd2+, Co2+, Zn2+, appropriate the Freundlich isotherm model and sequence of biosorption % was explained for the ratio of the hydration number to the hydrated radii of these metals. Biosorption results indicated that HC can be used for removing metal ions from aqueous solutions.