Synthesis of p-methoxyphenacylmethacrylate: its characterization, polymerization and preparation of the oxime and 2,4-dinitrophenylhydrazone derivatives

SOYKAN C., Ozdemir E. , Ahmedzade M.

REACTIVE & FUNCTIONAL POLYMERS, cilt.47, sa.2, ss.87-92, 2001 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 47 Konu: 2
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1016/s1381-5148(00)00069-9
  • Sayfa Sayıları: ss.87-92


p-Methoxyphenacylmethacrylate (MPMA) was prepared from p-methoxyphenacylbromide and sodium methacrylate. Polymerization of the monomer was carried out in 1,4-dioxane solution in presence of 2,2'-azobisisobutyronitrile as an initiator at 70 degreesC. The monomer and the polymer microstructure were investigated by FT-IR, H-1-NMR and C-13-NMR techniques. The oxime and hydrazone derivatives of poly(MPMA) were also prepared and characterized by FT-IR, TGA and DSC. (C) 2001 Elsevier Science B.V. All rights reserved.