Synthesis of p-methoxyphenacylmethacrylate: its characterization, polymerization and preparation of the oxime and 2,4-dinitrophenylhydrazone derivatives

SOYKAN C., Ozdemir E., Ahmedzade M.

REACTIVE & FUNCTIONAL POLYMERS, vol.47, no.2, pp.87-92, 2001 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 47 Issue: 2
  • Publication Date: 2001
  • Doi Number: 10.1016/s1381-5148(00)00069-9
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.87-92
  • Çanakkale Onsekiz Mart University Affiliated: Yes


p-Methoxyphenacylmethacrylate (MPMA) was prepared from p-methoxyphenacylbromide and sodium methacrylate. Polymerization of the monomer was carried out in 1,4-dioxane solution in presence of 2,2'-azobisisobutyronitrile as an initiator at 70 degreesC. The monomer and the polymer microstructure were investigated by FT-IR, H-1-NMR and C-13-NMR techniques. The oxime and hydrazone derivatives of poly(MPMA) were also prepared and characterized by FT-IR, TGA and DSC. (C) 2001 Elsevier Science B.V. All rights reserved.