A new selective fluorescent sensor for Zn(II) ions based on poly(azomethine-urethane)

Avci A., KAYA İ.

TETRAHEDRON LETTERS, vol.56, no.14, pp.1820-1824, 2015 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 56 Issue: 14
  • Publication Date: 2015
  • Doi Number: 10.1016/j.tetlet.2015.02.079
  • Journal Name: TETRAHEDRON LETTERS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1820-1824
  • Keywords: Poly(azomethine-urethane), Zn(II) sensor, Fluorescence sensor, Optical sensor
  • Çanakkale Onsekiz Mart University Affiliated: Yes

Abstract

A new and selective fluorescent sensor based on poly(azomethine-urethane) (PAMU) is synthesized and characterized by FT-IR, H-1 NMR, and size exclusion chromatography (SEC) techniques. The new sensor shows a high selectivity for Zn(II) over other metal cations in DMF/deionized H2O (1:2, v/v). The fluorescence sensor gives a linearly and highly stable response to Zn(II) as an increasing emission peak at 595 nm. The sensitivity limit of the new sensor is found to be 11.4 x 10(-3) mol L-1. The results show that the proposed sensor can be efficiently used as a simple method for the detection of Zn(II) ions. (C) 2015 Elsevier Ltd. All rights reserved.