A new selective fluorescent sensor for Zn(II) ions based on poly(azomethine-urethane)

Avci A., KAYA İ.

TETRAHEDRON LETTERS, cilt.56, sa.14, ss.1820-1824, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 56 Sayı: 14
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1016/j.tetlet.2015.02.079
  • Dergi Adı: TETRAHEDRON LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1820-1824
  • Anahtar Kelimeler: Poly(azomethine-urethane), Zn(II) sensor, Fluorescence sensor, Optical sensor
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

A new and selective fluorescent sensor based on poly(azomethine-urethane) (PAMU) is synthesized and characterized by FT-IR, H-1 NMR, and size exclusion chromatography (SEC) techniques. The new sensor shows a high selectivity for Zn(II) over other metal cations in DMF/deionized H2O (1:2, v/v). The fluorescence sensor gives a linearly and highly stable response to Zn(II) as an increasing emission peak at 595 nm. The sensitivity limit of the new sensor is found to be 11.4 x 10(-3) mol L-1. The results show that the proposed sensor can be efficiently used as a simple method for the detection of Zn(II) ions. (C) 2015 Elsevier Ltd. All rights reserved.