Thermal studies of Co(II), Ni(II) and Cu(II) complexes of N,N'-bis(3,5-Di-t-butylsalicylidene)ethylenediamine


DOĞAN F. , ULUSOY M. S. , ÖZTÜRK O. C. , KAYA İ. , SALİH B.

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, cilt.96, ss.267-276, 2009 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 96 Konu: 1
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1007/s10973-008-8980-8
  • Dergi Adı: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Sayfa Sayıları: ss.267-276

Özet

The thermal decomposition kinetics of sterically hindered salen type ligand (L) and its metal complexes [M=Co(II), Ni(II), Cu(II)] were investigated by thermogravimetric analysis. A direct insertion probe-mass spectrometer (DIP-MS) was used for the characterization of metal complexes of L and all fragmentations and stable ions were characterized. The thermogravimetry and differential thermogravimetry (TG-DTG) plots of salen type salicylaldimine ligand and complexes showed a single step.