Synthesis of Metal-Coordinated Poly(azomethine-urethane)s: Thermal Stability, Optical and Electrochemical Properties


Kamaci M., KAYA İ.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, cilt.23, ss.1159-1171, 2013 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 23 Konu: 5
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1007/s10904-013-9908-8
  • Dergi Adı: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
  • Sayfa Sayıları: ss.1159-1171

Özet

In this study, the novel thermally stable metal-coordinated-poly(azomethine-urethane)s (PAMU-M)s were synthesized to investigate some physical properties such as thermal stability, optical and electrochemical properties. For this reason, we firstly synthesized the Schiff base via condensation reaction of p-phenylenediamine with 2,4-dihydroxy benzaldehyde. Secondly, metal-coordinated Schiff bases were synthesized by coordination reaction of the obtained Schiff base and different metal ions such as Cu(II), Ni(II), Pb(II) and Zn(II). Then, these metal-coordinated Schiff bases were converted to their PAMU derivatives by the step-polymerization reaction using 2,4-toluenediisocyanate. Also, thermal stability, electrochemical and optic properties of the obtained materials were investigated.