Synthesis of Metal-Coordinated Poly(azomethine-urethane)s: Thermal Stability, Optical and Electrochemical Properties

Kamaci M., KAYA İ.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, vol.23, no.5, pp.1159-1171, 2013 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 23 Issue: 5
  • Publication Date: 2013
  • Doi Number: 10.1007/s10904-013-9908-8
  • Journal Name: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1159-1171
  • Keywords: Thermal properties, Optical properties, Luminescence, Electrochemical properties, Polymers-metals, SCHIFF-BASE, PHYSICAL-PROPERTIES, ANTIMICROBIAL PROPERTIES, MAIN-CHAIN, POLYURETHANE, COMPLEXES, DERIVATIVES, COMPOSITES, PHENOL
  • Çanakkale Onsekiz Mart University Affiliated: Yes

Abstract

In this study, the novel thermally stable metal-coordinated-poly(azomethine-urethane)s (PAMU-M)s were synthesized to investigate some physical properties such as thermal stability, optical and electrochemical properties. For this reason, we firstly synthesized the Schiff base via condensation reaction of p-phenylenediamine with 2,4-dihydroxy benzaldehyde. Secondly, metal-coordinated Schiff bases were synthesized by coordination reaction of the obtained Schiff base and different metal ions such as Cu(II), Ni(II), Pb(II) and Zn(II). Then, these metal-coordinated Schiff bases were converted to their PAMU derivatives by the step-polymerization reaction using 2,4-toluenediisocyanate. Also, thermal stability, electrochemical and optic properties of the obtained materials were investigated.