Novel non-aggregated soluble metallophthalocyanines bearing carboxylic acid groups


Bayar S., Dincer H. A. , Ugur A. L.

JOURNAL OF COORDINATION CHEMISTRY, vol.65, no.8, pp.1371-1380, 2012 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 65 Issue: 8
  • Publication Date: 2012
  • Doi Number: 10.1080/00958972.2012.673124
  • Title of Journal : JOURNAL OF COORDINATION CHEMISTRY
  • Page Numbers: pp.1371-1380

Abstract

Synthesis and characterization of zinc and cobalt phthalocyanines substituted with biphenylmethylpropionic acids, methyl-o-tolylpropionic acids, and methyl-p-tolylpropionic acids are described in this study. The new compounds have been characterized by elemental analyses, FT-IR, UV-Vis, MALDI-TOF, and H-1 NMR spectroscopy. All new compounds are soluble in THF, DMF, DMSO, and dilute sodium hydroxide solution. The influence of the carboxylic acid and bulky biphenyl, ortho-methylbenzyl and para-methylbenzyl groups on the spectroscopic properties has been investigated. UV-Vis experiments suggest that the tendency of phthalocyanines to aggregate in polar solvents is significantly reduced owing to the carboxylic acid groups and bulky peripheral substituents.