Electrochemical behaviour of 5-benzyl-4-(4'-methylphenyl)-4H-1,2,4-triazole-3-thiol by voltammetry


Dilgin Y. , KOPARIR M., CETIN A., CANSIZ A., Yilmaz S., GIRAY D.

JOURNAL OF THE INDIAN CHEMICAL SOCIETY, vol.84, no.10, pp.1024-1025, 2007 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 84 Issue: 10
  • Publication Date: 2007
  • Title of Journal : JOURNAL OF THE INDIAN CHEMICAL SOCIETY
  • Page Numbers: pp.1024-1025

Abstract

The electrochemical study of a thiotriazole compound, 5-benzyl-4-(4'-methylphenyl-4H-1,2,4-triazole-3-thioI (TTA) was made with cyclic voltammetry (CV) and differential pulse voltammetry (DPV) using glassy carbon electrode (GCE) as working electrode and an Ag/AgCl reference electrode in the Britton- Robinson buffer. The best results for electrooxidation of TTA were obtained in basic media (in 10% ethanol-0.2 M NaOH). This compound display one irreversible oxidation peak, which is attributed to a dimerization process involving the formation of disulphide derivative (EC mechanism).