Sensitive, Accurate and Selective Determination of Cd(II) Using Anodic Stripping Voltammetry With In-situ Hg-Bi Film Modified Pencil Graphite Electrode After Magnetic Dispersive Solid Phase Microextraction

Yaman B., Zaman B. T., BAKIRDERE S., DİLGİN Y.

ELECTROANALYSIS, vol.33, no.10, pp.2161-2168, 2021 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 33 Issue: 10
  • Publication Date: 2021
  • Doi Number: 10.1002/elan.202100228
  • Journal Name: ELECTROANALYSIS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Applied Science & Technology Source, BIOSIS, Chemical Abstracts Core, Chimica, Communication Abstracts, Metadex, Civil Engineering Abstracts
  • Page Numbers: pp.2161-2168
  • Keywords: Cadmium, dispersive solid phase microextraction, graphite pencil electrode., magnetic nanoparticles, stripping voltammetry
  • Çanakkale Onsekiz Mart University Affiliated: Yes

Abstract

This paper describes a novel approach to detect Cd(II) using the combination of the differential pulse anodic stripping voltammetry and magnetic nanoparticle based dispersive solid phase microextraction as an efficient, green and accurate method. Currents of Cd(II) increased linearly in the range from 75 to 2000 ngL(-1) Cd(II) with a detection limit of 21.6 ngL(-1). The RSD values of 2.6 and 6.0 % for 1.00 and 0.10 mu g L-1 respectively showed that proposed method has an acceptable repeatability. Recovery values between 92.3 and 98.6 % showed that this approach can be successfully used for determination of Cd(II) in water samples.