Spectroscopic and electrochemical behavior of the novel tetra-2-methyl-pyrazinoporphyrazines

PİŞKİN M., ÖZTÜRK N., DURMUŞ M.

JOURNAL OF MOLECULAR STRUCTURE, cilt.1149, ss.893-899, 2017 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 1149
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1016/j.molstruc.2017.08.053
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.893-899
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

This study presents the synthesis and characterization of novel metal-free (H2Pc) and metallo porphyrazines (magnesium(II) (MgPz), copper(II) (CuPz), iron(II) (FePz), manganese(II) (MnPz) and nickel(II) (NiPz)) substituted with four 2-methylpyrazine groups on the peripheral positions. The spectroscopic properties of newly synthesized porphyrazines were investigated. The electrochemical behaviors of these porphyrazines were also determined in DMSO solution by cyclic voltammetry (CV) and square wave voltammetry (SWV) methods on edge plane pyrolytic graphite electrode (EPPG) electrode. (C) 2017 Published by Elsevier B.V.