Spectroscopic and electrochemical behavior of the novel tetra-2-methyl-pyrazinoporphyrazines

PİŞKİN M., ÖZTÜRK N., DURMUŞ M.

JOURNAL OF MOLECULAR STRUCTURE, vol.1149, pp.893-899, 2017 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 1149
  • Publication Date: 2017
  • Doi Number: 10.1016/j.molstruc.2017.08.053
  • Journal Name: JOURNAL OF MOLECULAR STRUCTURE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.893-899
  • Çanakkale Onsekiz Mart University Affiliated: Yes

Abstract

This study presents the synthesis and characterization of novel metal-free (H2Pc) and metallo porphyrazines (magnesium(II) (MgPz), copper(II) (CuPz), iron(II) (FePz), manganese(II) (MnPz) and nickel(II) (NiPz)) substituted with four 2-methylpyrazine groups on the peripheral positions. The spectroscopic properties of newly synthesized porphyrazines were investigated. The electrochemical behaviors of these porphyrazines were also determined in DMSO solution by cyclic voltammetry (CV) and square wave voltammetry (SWV) methods on edge plane pyrolytic graphite electrode (EPPG) electrode. (C) 2017 Published by Elsevier B.V.