Analysis of the peak position and linewidth as a function of temperature for the phase transitions in LiKSO4


YURTSEVEN H. H. , KURT M.

MODERN PHYSICS LETTERS B, cilt.30, 2016 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 30 Konu: 5
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1142/s0217984916500160
  • Dergi Adı: MODERN PHYSICS LETTERS B

Özet

Analysis of the peak position and the linewidths of various infrared modes is performed at high (300-850 K) and low (1.5-300 K) temperatures using the experimental data from the literature for LiKSO4 which exhibits a sequence of phase transitions. The temperature dependences of the frequency and the linewidth which are derived from the anharmonic self-energy are fitted to the observed peak positions and the linewidths of the S-O stretching modes (internal nu(3) modes at 1135 cm(-1) and at 1180 cm(-1)), peak position of the S-O bending nu(4) (internal) modes, the peak position and the linewidth of the Li mode at 429 cm(-1) (external mode), and of the infrared band at 363 cm(-1) for LiKSO4.