Direct Photopatterning of BODIPY-Based Small Molecules via Thiol-ene Click Chemistry

ÖZDEMİR M., ALTINIŞIK S., Ömeroğlu İ., Köksoy B., Durmuş M., YALÇIN B., ...Daha Fazla

ChemNanoMat, cilt.9, sa.1, 2023 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 9 Sayı: 1
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1002/cnma.202200295
  • Dergi Adı: ChemNanoMat
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Applied Science & Technology Source, Chemical Abstracts Core, Compendex
  • Anahtar Kelimeler: BODIPY, electrochemistry, photopatterning, surface characterization, thiol-ene click
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

© 2022 Wiley-VCH GmbH.We demonstrate a BODIPY-based small molecule photopatterned surface by thiol-ene click chemistry at room temperature utilizing only 366 nm UV light. The resulting cross-linked polymer exhibits porous surfaces according to AFM and TEM results. A dramatic blue shift occurred in absorption spectra and the photoluminescence was also intensified as a result of crosslinking. Optical and electrochemical results are compatible with the DFT calculations. The obtained results prove that the photopatterned BODIPY-based material can be easily and inexpensively applied in multilayer optoelectronic devices.