Direct Photopatterning of BODIPY-Based Small Molecules via Thiol-ene Click Chemistry
ChemNanoMat, cilt.9, sa.1, 2023 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 9 Sayı: 1
- Basım Tarihi: 2023
- Doi Numarası: 10.1002/cnma.202200295
- Dergi Adı: ChemNanoMat
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Applied Science & Technology Source, Chemical Abstracts Core, Compendex
- Anahtar Kelimeler: BODIPY, electrochemistry, photopatterning, surface characterization, thiol-ene click
- Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet
Özet
© 2022 Wiley-VCH GmbH.We demonstrate a BODIPY-based small molecule photopatterned surface by thiol-ene click chemistry at room temperature utilizing only 366 nm UV light. The resulting cross-linked polymer exhibits porous surfaces according to AFM and TEM results. A dramatic blue shift occurred in absorption spectra and the photoluminescence was also intensified as a result of crosslinking. Optical and electrochemical results are compatible with the DFT calculations. The obtained results prove that the photopatterned BODIPY-based material can be easily and inexpensively applied in multilayer optoelectronic devices.