Synthesis and Characterization of Novel Polyamines Containing Different Substitute Groups Via Chemical Oxidative Polymerization


ŞENOL BAHÇECİ D., KAYA İ.

JOURNAL OF THE CHINESE CHEMICAL SOCIETY, vol.62, no.5, pp.429-438, 2015 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 62 Issue: 5
  • Publication Date: 2015
  • Doi Number: 10.1002/jccs.201400525
  • Journal Name: JOURNAL OF THE CHINESE CHEMICAL SOCIETY
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.429-438

Abstract

In this study, polymers of substitute aromatic amine compounds were synthesized by chemical oxidative polycondensation in aqueous alkaline medium using NaOCl as oxidant. The structures of synthesized compounds were confirmed by FT-IR, UV-Vis and NMR analyses. The characterizations of synthesized compounds were made by fluorescence, TG-DTA, DSC, scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) surface area measurements. In addition, electrochemical and electrical conductivity values of compounds were carried out with cyclic voltammetry (CV) and four points probe technique measurements, respectively. Synthesized polymers viewed structural change, optical, electrochemical and thermal differences.