Synthesis and Characterization of Novel Polyamines Containing Different Substitute Groups Via Chemical Oxidative Polymerization

ŞENOL BAHÇECİ D., KAYA İ.

JOURNAL OF THE CHINESE CHEMICAL SOCIETY, cilt.62, sa.5, ss.429-438, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 62 Sayı: 5
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1002/jccs.201400525
  • Dergi Adı: JOURNAL OF THE CHINESE CHEMICAL SOCIETY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.429-438
  • Anahtar Kelimeler: Oxidative polycondensation, Substituted aromatic amines, Thermal analysis, Electrical conductivity, Band gap
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

In this study, polymers of substitute aromatic amine compounds were synthesized by chemical oxidative polycondensation in aqueous alkaline medium using NaOCl as oxidant. The structures of synthesized compounds were confirmed by FT-IR, UV-Vis and NMR analyses. The characterizations of synthesized compounds were made by fluorescence, TG-DTA, DSC, scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) surface area measurements. In addition, electrochemical and electrical conductivity values of compounds were carried out with cyclic voltammetry (CV) and four points probe technique measurements, respectively. Synthesized polymers viewed structural change, optical, electrochemical and thermal differences.