Octakis (9-anthracenylmethylthio) iron porphyrazine derivatives


Gonca E.

JOURNAL OF CHEMICAL RESEARCH-S, no.8, pp.465-467, 2008 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: Issue: 8
  • Publication Date: 2008
  • Doi Number: 10.3184/030823408x340582
  • Title of Journal : JOURNAL OF CHEMICAL RESEARCH-S
  • Page Numbers: pp.465-467

Abstract

Chloro[octakis(9-anthracenylmethylthio)porphyrazinato]iron(III), ([FePzCl]), was prepared by the reaction of metal-free porphyrazine with iron(II) acetate and further treatment with HCl solution. The monomeric bisaxial complex [FePz(py)(2)] as well as the bridged complex [FePz(pyz)](n) were formed as stable complexes by reacting [FePzCl] with pyridine or pyrazine, respectively. These novel complexes were characterised by elemental analysis, together with FT-IR, (1)H NMR, UV-Vis and mass spectral data.