Octakis (9-anthracenylmethylthio) iron porphyrazine derivatives


Gonca E.

JOURNAL OF CHEMICAL RESEARCH-S, ss.465-467, 2008 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: Konu: 8
  • Basım Tarihi: 2008
  • Doi Numarası: 10.3184/030823408x340582
  • Dergi Adı: JOURNAL OF CHEMICAL RESEARCH-S
  • Sayfa Sayıları: ss.465-467

Özet

Chloro[octakis(9-anthracenylmethylthio)porphyrazinato]iron(III), ([FePzCl]), was prepared by the reaction of metal-free porphyrazine with iron(II) acetate and further treatment with HCl solution. The monomeric bisaxial complex [FePz(py)(2)] as well as the bridged complex [FePz(pyz)](n) were formed as stable complexes by reacting [FePzCl] with pyridine or pyrazine, respectively. These novel complexes were characterised by elemental analysis, together with FT-IR, (1)H NMR, UV-Vis and mass spectral data.