The new zinc(II) phthalocyanine directly conjugated with 4-butylmorpholine units: Synthesis, characterization, thermal, spectroscopic and photophysical properties

Mutlu F., PİŞKİN M., CANPOLAT E., ÖZTÜRK Ö. F.

JOURNAL OF MOLECULAR STRUCTURE, cilt.1201, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 1201
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1016/j.molstruc.2019.127169
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, Compendex, INSPEC
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

In this study, new peripheral tetra-4-butylmorpholine substituted zinc(II) phthalocyanine was synthesized through C-C bond formation using the palladium catalyzed Suzuki-Miyaura coupling reaction. Its structure was characterized by elemental analysis, FT-IR, H-1 NMR, C-13 NMR, UV-vis, fluorescence, and MALDI-TOF-mass spectroscopic techniques. Its thermal property were evaluated by thermogravimetric analysis and differential scanning calorimetry. In addition, the photophysical properties of the zinc(II) phthalocyanine were also investigated in DMSO. (C) 2019 Published by Elsevier B.V.