The new zinc(II) phthalocyanine directly conjugated with 4-butylmorpholine units: Synthesis, characterization, thermal, spectroscopic and photophysical properties


Mutlu F., PİŞKİN M., CANPOLAT E., ÖZTÜRK Ö. F.

JOURNAL OF MOLECULAR STRUCTURE, vol.1201, 2020 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 1201
  • Publication Date: 2020
  • Doi Number: 10.1016/j.molstruc.2019.127169
  • Journal Name: JOURNAL OF MOLECULAR STRUCTURE
  • Journal Indexes: Science Citation Index Expanded, Scopus, Academic Search Premier, Chimica, Compendex, INSPEC

Abstract

In this study, new peripheral tetra-4-butylmorpholine substituted zinc(II) phthalocyanine was synthesized through C-C bond formation using the palladium catalyzed Suzuki-Miyaura coupling reaction. Its structure was characterized by elemental analysis, FT-IR, H-1 NMR, C-13 NMR, UV-vis, fluorescence, and MALDI-TOF-mass spectroscopic techniques. Its thermal property were evaluated by thermogravimetric analysis and differential scanning calorimetry. In addition, the photophysical properties of the zinc(II) phthalocyanine were also investigated in DMSO. (C) 2019 Published by Elsevier B.V.