CYCLIC CASCADE CARBOPALLADATION REACTIONS AS A ROUTE TO BENZENE AND FULVENE DERIVATIVES


Negishi E., Harring L. S. , Owczarczyk Z., Mohamud M. M. , AY M.

TETRAHEDRON LETTERS, vol.33, no.23, pp.3253-3256, 1992 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 33 Issue: 23
  • Publication Date: 1992
  • Doi Number: 10.1016/s0040-4039(00)92060-4
  • Journal Name: TETRAHEDRON LETTERS
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.3253-3256

Abstract

Palladium-catalyzed cyclization of appropriately structured triynes, haloalkenyldiynes, or haloalkenylalkyne-alkyne mixtures can provide the corresponding benzene derivatives, while the Pd-catalyzed intermolecular reaction of diynes with alkenyl halides can give fulvene derivatives.