Spectroscopic studies and structure of 3-methoxy-2-[(2,4,4,6,6-pentachloro-1,3,5,2 lambda(5),4 lambda(5),6 lambda(5)-triazatriphosphin-2-yl)oxy]benzaldehyde

ÖZAY H., YILDIZ M., Unver H., Durlu T. N.

CRYSTALLOGRAPHY REPORTS, vol.58, no.1, pp.102-105, 2013 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 58 Issue: 1
  • Publication Date: 2013
  • Doi Number: 10.1134/s1063774513010252
  • Journal Name: CRYSTALLOGRAPHY REPORTS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.102-105
  • Çanakkale Onsekiz Mart University Affiliated: Yes

Abstract

The compound called 3-methoxy-2-[(2,4,4,6,6-pentachloro-1,3,5,2 lambda(5),4 lambda(5),6 lambda(5)-triazatriphosphin-2-yl)oxy]benzaldehyde has been synthesized from the reaction of 2-hydroxy-3-methoxybenzaldehyde with hexachlorocyclotriphosphazene. It has been characterized by elemental analysis, MS, IR, H-1 NMR, C-13 NMR, P-31 NMR and UV-visible spectroscopic techniques. The structure of the title compound has been determind by X-ray analysis. Crystals are orthorhombic, space group P2(1)2(1)2(1), Z = 4, a = 7.705(1), b = 12.624(1), c = 17.825(2) , R (1) = 0.0390 and wR (2) = 0.1074 [I > 2 sigma(I)], respectively.