Synthesis, Molecular Structure, Biological Activity, and Sensor Properties of (E)-2-[(3,5-Bis(trifluoromethyl)phenylimino)methyl]-4,6-dichlorophenol

Zeyrek C., Boyacıoğlu B., Demir N., Tümer Y., Kiraz A., Ünver H., ...Daha Fazla

Russian Journal of General Chemistry, cilt.91, sa.2, ss.279-284, 2021 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 91 Sayı: 2
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1134/s107036322102016x
  • Dergi Adı: Russian Journal of General Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core
  • Sayfa Sayıları: ss.279-284
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

© 2021, Pleiades Publishing, Ltd.Abstract: In the present study, a Schiff base (E)-2-[(3,5-bis(trifluoromethyl)phenylimino)methyl]-4,6-dichlorophenolhas been synthesized. Its spectroscopic and X-ray single-crystal data have beencompared with the results of theoretical calculations based on the DFT method,as well as molecular electrostatic potential (MEP), HOMO and LUMO, and nonlinearoptical (NLO) effects. Antimicrobial activity of the compound has been testedagainst some bacteria and fungi. According to UV-Vis and agarose gelelectrophoresis methods, the compound interacts with DNA electrostatically andbreaks it oxidatively. Antioxidant activity of the compound measured by the DPPHmethod, is lower than that of BHT.