3-carboxypyridinium trichloroacetatochromate (CPTCAC): as a mild and effective new reagent for the thiols to disulfides
JOURNAL OF CHEMICAL RESEARCH, sa.4, ss.224-226, 2005 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: Sayı: 4
- Basım Tarihi: 2005
- Doi Numarası: 10.0002/29953200005
- Dergi Adı: JOURNAL OF CHEMICAL RESEARCH
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.224-226
- Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet
Özet
A new chromium(VI) reagent, 3-carboxypyridinium trichloroacetatochromate (CPTCAC) was prepared by reacting 3-carboxypyridine (nicotinic acid) and trichloroacetic acid with CrO3 in water. This oxidising agent oxidised the thiols to disulfides selectivily and in very high yields.