Magnetically isolable Pd(0) nanoparticles supported on surface functionalized Fe3O4 for hydrogen generation via ammonia borane hydrolysis

Tercan M.

ChemistrySelect, cilt.8, sa.31, 2023 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 8 Sayı: 31
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1002/slct.202302035
  • Dergi Adı: ChemistrySelect
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier
  • Anahtar Kelimeler: Ammonia borane, Heterogenous catalyst, Hydrogen, Magnetite, Pd nanoparticles
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

Pd(0) nanoparticles supported on surface functionalized magnetite (Fe3O4/SiO2-NH2/HB@Pd) were prepared as catalyst for hydrolysis of ammonia borane (AB). The obtained magnetic nanocomposite material was seperated from the reaction media through a permanent magnet and characterized by FT-IR, XRD, SEM-EDX, TEM, ICP-OES and XPS techniques. 100 mg Fe3O4/SiO2−NH2/HB@Pd nanocomposite with Pd metal content of 6.00±0.14 catalyzed the hydrolysis of 10 mM AB at 25 °C with 100 % yield. The presented work includes the effect of catalyst amount and temperature on the rate of the hydrolysis reaction of AB. As a result of the kinetic studies, the activation energy (Ea) for the Fe3O4/SiO2−NH2/HB@Pd catalyzed AB hydrolysis reaction was calculated as 34±1 kJ.mol−1, and the TOF value was calculated as 133 mol H2.(mol Pd(0).h)−1. The designed heterogenous magnetic nanocomposite catalyst demonstrated significant catalytic activity for AB hydrolysis reaction at 25 °C.