Synthesis and characterization of a pyridine-containing Schiff base oligomer

Demir H. O., Kaya I., SACAK M.

RUSSIAN CHEMICAL BULLETIN, cilt.55, sa.10, ss.1852-1855, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 55 Sayı: 10
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1007/s11172-006-0497-3
  • Dergi Adı: RUSSIAN CHEMICAL BULLETIN
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1852-1855
  • Anahtar Kelimeler: oxygen, oxidative polycondensation, 4-(4-pyridylmethylideneimino)phenol, Schiff bases, oligomers
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

The oligomer of 4-(4-pyridylmethylideneimino)phenol was formed during oxidative polycondensation in aqueous alkaline medium using oxygen as the oxidant. Optimum conditions of the oxidative polycondensation and the main parameters of the process were found. The maximum yield of the oligomer was 52.4%. The product was characterized by elemental analysis, FT-IR spectroscopy, UV-Vis spectroscopy, and H-1 NMR spectroscopy. The molecular weight distribution was determined by size exclusion chromatography. Thermogravimetric and differential thermal analyses were carried out for 4-(4-pyridylmethylideneimino)phenol and its oligomer.