An ambipolar low band gap material based on BODIPY and EDOT


Algi F. , CİHANER A.

ORGANIC ELECTRONICS, cilt.10, ss.453-458, 2009 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 10 Konu: 3
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1016/j.orgel.2009.01.010
  • Dergi Adı: ORGANIC ELECTRONICS
  • Sayfa Sayıları: ss.453-458

Özet

A novel donor-acceptor type conducting polymer based on BODIPY dye as acceptor and EDOT units as donor parts is synthesized electrochemically. The unique combination of BODIPY and EDOT units provides an ambipolar (n- and p-doping processes) low band gap material (4). This is the first example of p-n junction in an organic pi-conjugated material where BODIPY unit is incorporated directly in the main chain. Furthermore, the polymer film exhibits electrochromic behavior upon p-doping: a color change from light violet (neutral) to indigo (oxidized). (C) 2009 Elsevier B.V. All rights reserved.