SYNTHESIS, CHARACTERIZATION, AND NAKED-EYE SENSOR APPLICATION OF FULLY SUBSTITUTED UREA-BASED CYCLOTRIPHOSPHAZENE COMPOUND


ÖZAY H., Yildirim M., ÖZAY Ö.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, vol.190, no.11, pp.1865-1873, 2015 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 190 Issue: 11
  • Publication Date: 2015
  • Doi Number: 10.1080/10426507.2015.1031752
  • Journal Name: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.1865-1873

Abstract

A novel sensor with a hexacenter containing nitrophenylurea groups on a cyclotriphosphazene core was synthesized by click reaction of N-propargyl-substituted urea with a hexaazide-substituted cyclotriphosphazene compound. It was characterized by spectroscopic techniques such as Fourier transform infrared spectroscopy, nuclear magnetic resonance, and mass spectroscopy. This compound was used for naked-eye and spectrophotometric detection of F- anions. The optical sensor properties of compound were investigated using ultraviolet-visible spectroscopy.