Synthesis, Characterization, and Crystal Structure of Bis[4-(3'-benzoyl)thiocarbamidophenyl] ether

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Aydın F., Aykaç D., Arslan N. B., Kazak C.

CRYSTALLOGRAPHY REPORTS, cilt.59, sa.7, ss.955-960, 2014 (SCI-Expanded)

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 59 Sayı: 7
  • Basım Tarihi: 2014
  • Dergi Adı: CRYSTALLOGRAPHY REPORTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.955-960
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

The title compound, bis[4(3'benzoyl)thiocarbamidophenyl]ether, was synthesized by the reac tion of benzoylisothiocyanate with 4,4'diaminodiphenylether in aprotic solvent. The structure was determi nated by means of elemental analysis and FT–IR, 1 H–NMR, 1 3C–NMR and MS spectroscopic techniques. The crystal structure was characterized by Xray syngle crystal analysis: orthorhombic, sp. gr. Pnna, Z = 4. In crystal packing, there are intramolecular hydrogen bond N–H⋅⋅⋅O generating S(6) motif, and intermolecular hydrogen bond N–H⋅⋅⋅S forming (8) ring.