Highly soluble 3,4-(dimethoxyphenylthio) substituted phthalocyanines: Synthesis, photophysical and photochemical studies

Ozturk, Cansu; ERDOĞMUŞ, Ali; Durmus, Mahmut; Ugur, AHMET; Kilicarslan, Fatma; ERDEN, İbrahim

doi:10.1016/j.saa.2011.10.062

Highly soluble 3,4-(dimethoxyphenylthio) substituted phthalocyanines: Synthesis, photophysical and photochemical studies

Atıf İçin Kopyala

Ozturk C., ERDOĞMUŞ A., Durmus M., Ugur A. L., Kilicarslan F. A., ERDEN İ.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, cilt.86, ss.423-431, 2012 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 86
Basım Tarihi: 2012
Doi Numarası: 10.1016/j.saa.2011.10.062
Dergi Adı: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.423-431
Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

The synthesis of a new 3,4-(dimethoxyphenylthio) substituted phthalonitrile (1) and its soluble metal free (2), zinc (II) (3), oxo-titanium (IV) (4) and nickel (II) (5) phthalocyanine derivatives are reported for the first time. The new compounds have been characterized by elemental analysis, FT-IR, H-1 NMR, UV-Vis, fluorescence spectroscopies and mass spectra. General trends are described for fluorescence, photodegradation and singlet oxygen quantum yields and fluorescence lifetimes of oxo-titanium (IV) and zinc (II) phthalocyanine compounds in dimethylsulfoxide (DMSO). The effects of the metal ion on the photophysical and photochemical parameters for these phthalocyanines (3 and 4) are also reported. (C) 2011 Elsevier B.V. All rights reserved.