VOLATILE ORGANIC VAPOR SENSING BEHAVIORS OF ORGANICΠ -Π* COMPLEXES THIN FILMS

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Şen S., Özbek Z., Aydın F., Çapan R.

40. Uluslararası TFD Fizik Kongresi, Muğla, Türkiye, 2 - 06 Eylül 2024, ss.108, (Özet Bildiri)

  • Yayın Türü: Bildiri / Özet Bildiri
  • Basıldığı Şehir: Muğla
  • Basıldığı Ülke: Türkiye
  • Sayfa Sayıları: ss.108
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

Charge transfer complex (CT complex) or electron donor-acceptor complex is defined as a material consisting of electrostatic attraction forces or chemical associations of two or more molecules or of different parts of one very large molecule.

Three organic π-π* charge transfer complexes formed from polynuclear aromatic hydrocrbons and picric acid such as anthracene picrate, phenanthrene picrate and pyrene picrate (Fig. 1 (a), (b) and (c)  respectively) were reorganized as thin films on quartz glass and 50 nm thick gold-coated glass substrates using the spin-coating method. For the characterization of the produced films, surface plasmon resonance (SPR) spectroscopy was used alongside UV-Vis spectroscopy. Subsequently, the films were exposed to benzene, chloroform, dicloromethane, acetone and ethanol vapors, and their sensor responses were examined in this study

 

(a) (b)                                                     (c)

Figure 1. Chemicalstructuresof (a) Anthracene picrate, (b) Phenanthrene picrate and (c) Pyrene picrate.

 

This study was supported by Çanakkale Onsekiz Mart University, Scientific Research Projects Unit (BAP-COMU) with the Proje code FBA-2023-4425.