New soluble porphyrazine derivatives containing electron-rich substituents


GONCA E.

JOURNAL OF COORDINATION CHEMISTRY, cilt.66, ss.1720-1729, 2013 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 66 Konu: 10
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1080/00958972.2013.790018
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Sayfa Sayıları: ss.1720-1729

Özet

Hydroxypropylsulfanyl groups of metal-free and metallo-porphyrazines (M=2H, Mg, Cu, Zn, or Co) have been prepared by the esterification with a carboxylate such as 1-naphthoic acid. The symmetrically functionalized porphyrazines with eight ester units were soluble in common organic solvents such as CHCl3, CH2Cl2, tetrahydrofuran, acetone, and toluene and insoluble in water and n-hexane. The compounds have been characterized by FT-IR, UVVis, mass, H-1, C-13 NMR, and elemental analysis.