Spectroscopic and structural properties of N-(acetamide) morpholinium bromide


Baran Y. , ÖZAY H. , Esener H., Turkyilmaz M.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, cilt.81, ss.99-103, 2011 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Cilt numarası: 81 Konu: 1
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1016/j.saa.2011.05.055
  • Dergi Adı: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Sayfa Sayıları: ss.99-103

Özet

A new crystal of N-(acetamide) morpholinium (NAM) bromide has been prepared in methanol at room temperature and characterized by single crystal X-ray analysis, elemental analysis, GS-MS, FUR, NMR((1)H, (13)C, DEPTH and HETCOR). The N-(acetamide) morpholinium crystallizes in the orthorhombic crystal system, Pnma with unit cell a = 12.798(9) angstrom, b = 7.222(5) angstrom, c = 9.244(5) angstrom, beta = 90.00, V = 854.4(9) angstrom(3), Z = 4. The X-ray structure determination revealed that there are strong inner and intermolecular hydrogen bonds in the crystal. (C) 2011 Elsevier B.V. All rights reserved.
A new crystal of N-(acetamide) morpholinium (NAM) bromide has been prepared in methanol at room temperature and characterized by single crystal X-ray analysis, elemental analysis, GS-MS, FTIR, NMR(1H,13C, DEPTH and HETCOR). The N-(acetamide) morpholinium crystallizes in the orthorhombic crystal system, Pnma with unit cell a = 12.798(9) Å, b = 7.222(5) Å, c = 9.244(5) Å, ß = 90.00, V = 854.4(9) Å3, Z = 4. The X-ray structure determination revealed that there are strong inner and intermolecular hydrogen bonds in the crystal.