Spectroscopic and structural properties of N-(acetamide) morpholinium bromide


Baran Y., ÖZAY H., Esener H., Turkyilmaz M.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, vol.81, no.1, pp.99-103, 2011 (SCI-Expanded) identifier identifier identifier

Abstract

A new crystal of N-(acetamide) morpholinium (NAM) bromide has been prepared in methanol at room temperature and characterized by single crystal X-ray analysis, elemental analysis, GS-MS, FTIR, NMR(1H,13C, DEPTH and HETCOR). The N-(acetamide) morpholinium crystallizes in the orthorhombic crystal system, Pnma with unit cell a = 12.798(9) Å, b = 7.222(5) Å, c = 9.244(5) Å, ß = 90.00, V = 854.4(9) Å3, Z = 4. The X-ray structure determination revealed that there are strong inner and intermolecular hydrogen bonds in the crystal.
A new crystal of N-(acetamide) morpholinium (NAM) bromide has been prepared in methanol at room temperature and characterized by single crystal X-ray analysis, elemental analysis, GS-MS, FUR, NMR((1)H, (13)C, DEPTH and HETCOR). The N-(acetamide) morpholinium crystallizes in the orthorhombic crystal system, Pnma with unit cell a = 12.798(9) angstrom, b = 7.222(5) angstrom, c = 9.244(5) angstrom, beta = 90.00, V = 854.4(9) angstrom(3), Z = 4. The X-ray structure determination revealed that there are strong inner and intermolecular hydrogen bonds in the crystal. (C) 2011 Elsevier B.V. All rights reserved.