Study of Interaction and Solubility Parameters of Alkyl Methacrylate Polymers by Inverse Gas Chromatography

KAYA İ., Ozdemir E., Coskun M.

TURKISH JOURNAL OF CHEMISTRY, vol.20, no.5, pp.11-19, 1996 (SCI-Expanded, Scopus, TRDizin) identifier

  • Publication Type: Article / Article
  • Volume: 20 Issue: 5
  • Publication Date: 1996
  • Journal Name: TURKISH JOURNAL OF CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Page Numbers: pp.11-19
  • Çanakkale Onsekiz Mart University Affiliated: No

Abstract

Flory-Huggins interaction parameters (x) and partial molar free energies of mixing (Delta G(1)(infinity)) have been determined by inverse gas chromatography (i.g.c.) at temperatures 413-443 K for alkanes, acetates, ketones, aromatics, THF and methanol to estimate the polymer solubility parameters (delta(2)) of PMMA, PEMA, PIBMA and Pt -BMA. Furthermore, weight fraction activity coefficients (alpha l/w(1))(infinity) of probes were calculated at infinite dilution at 413-443 K.