Ag(0) nanocatalyst stabilized with networks of p(SPA-co-AMPS) for the hydrogen generation process from ethylenediamine bisborane hydrolysis

Durgut S., Özay H.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, cilt.45, ss.17649-17661, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 45
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1016/j.ijhydene.2020.04.248
  • Dergi Adı: INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Artic & Antarctic Regions, Chimica, Communication Abstracts, Compendex, Environment Index, INSPEC
  • Sayfa Sayıları: ss.17649-17661
  • Anahtar Kelimeler: Ethylenediamine bisborane, Hydrogen generation, Hydrogel, Silver, Ag(0), Catalyst, CORE-SHELL NANOPARTICLES, AMMONIA-BORANE, THERMAL DEHYDROGENATION, EXPERIMENTAL INSIGHTS, CATALYTIC HYDROLYSIS, EFFICIENT CATALYST, STORAGE MATERIALS, SUPPORT MATERIAL, GRAPHENE OXIDE, SILVER
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

In this study, the hydrogen generation from the catalytic hydrolysis of the ethylenediamine bisborane (EDAB) was performed. For this purpose, the p(sulfopropyl acrylate potassium salt-co-2-acrylamido-2-methylpropansulfonic acid sodium salt)@Ag(0) (p(SPA-co-AMPS)@Ag) catalyst was prepared. Later the p(SPA-co-AMPS)@Ag containing Ag(0) particles with nanodimensions was used as catalyst in EDAB hydrolysis. Our study is the first in the literature from this aspect, and investigated in detail the effect of catalyst amount, reactive concentration, temperature and dry or swollen nature of the catalyst on the EDAB hydrolysis. At the end of the reaction series, the hydrolysis reaction of EDAB with p(SPA-co-AMPS)@Ag catalyst was determined to have activation energy (E-a) of 43.24 kJmol(-1). Additionally, the turn over frequency (TOF) was 0.560 mol H-2(mol Ag(0).min)(-1) at 30 degrees C. The p(SPA-co-AMPS)@Ag catalyst had perfect reusability with 95% of initial activity after the 5th use for the hydrogen generation from EDAB. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.