A comparative study of 9,9-bis(4-aminophenyl)fluorene polymers prepared by catalytic and non-catalytic oxidative polymerisation methods

BİLİCİ A., KAYA İ., Yildirim M.

EUROPEAN POLYMER JOURNAL, cilt.47, sa.5, ss.1005-1017, 2011 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 47 Sayı: 5
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1016/j.eurpolymj.2011.02.019
  • Dergi Adı: EUROPEAN POLYMER JOURNAL
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1005-1017
  • Anahtar Kelimeler: Polyfluorene, Oxidative polymerisation, Optical properties, Conductivity, Cyclic voltammetry
  • Çanakkale Onsekiz Mart Üniversitesi Adresli: Evet

Özet

9.9-Bis(4-aminophenyl)fluorene (APF) polymers were synthesized by two different pathways. The different synthetic routes gave polymers with different structures. FT-IR and NMR studies revealed that the catalytic oxidative polymerisation of APF in acetonitrile produced P2, whereas oxidative polymerisation of APF in aqueous alkaline media gave P3. The effects of these different techniques on spectral, thermal, optical, electrical, electrochemical, and morphological properties of resulting polymers were investigated. (C) 2011 Elsevier Ltd. All rights reserved.
9,9-Bis(4-aminophenyl)fluorene (APF) polymers were synthesized by two different pathways. The different synthetic routes gave polymers with different structures. FT-IR and NMR studies revealed that the catalytic oxidative polymerisation of APF in acetonitrile produced P2, whereas oxidative polymerisation of APF in aqueous alkaline media gave P3. The effects of these different techniques on spectral, thermal, optical, electrical, electrochemical, and morphological properties of resulting polymers were investigated.